![]() Hydrogen bonds are usually showed as dotted lines between two atoms. This is a very weak bond and strength of hydrogen bond (5-10 Kcal per bond) is much less than the strength of covalent bond. Ionic bonds are not as strong as covalent, which determines their. (The statement is a fairly complete definition of the hydrogen bond Hydration shell refers to organization of water molecules around a non-polar group "Hydrophobic Bond" is not a real term, don't confuse it with a "hydrogen bond" Partial charges cannot be involved in ionic bonds, only full charges can form ionic bonds.)Ģ. Hydrogen bond is an attractive force between a partially positive charged hydrogen and a partially negative charged atom (oxygen and nitrogen). Ionic and covalent bonds between elements require energy to break. Micelles will form spontaneous driven by the hydrophobic effect.ġ. The partial negative charge at one end of a water molecule is attracted to the partial positive charge of another water molecule. Micelles are aggregates of amphipathic molecules that sequester the nonpolar part on the inside, much like the inside of an orange. Hydrogen bonds have considerable importance in biochemistry. These can form micelles if the nonpolar part is sufficiently large. An example is a fatty acid, which has a charged carboxylate (red) and a non-polar hydrocarbon chain (yellow). CompoundĪmphipathic (or amphiphilic) compounds are both polar (or charged) and nonpolar. ![]() A large dipole moment means that the solvent molecules can interact favorably with charged solute molecules. The dielectric constant is proportional to the dipole moment of the solvent, as the dipole moment increases, D, increases, as shown in the following table. ![]()
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![]() With the right ad blocker for your devices, you can improve your productivity and escape the anonymous bunch of ads on the web. ![]() With a proper ad blocker in place, ad distractions become a thing of the past.Īfter privacy and productivity, users should be aware of the malware, spyware, and adware that can infiltrate a system through anonymous ads, along with freeware that can be displayed as pop-ups.Īds, once clicked, can automatically trigger a command & control server configuration, thus utilizing the vulnerability in your system to deploy malware into that particular system. This can affect the productivity of an organization if more employees fall victim to ads. Unknown ads are being shown and this breaches user privacy.Īn employee at work can easily get distracted when exposed to ads that are attractive and influential. Merry Christmas from AdLock team Keep your loved ones secure and safe in a new year. Pricing 60 months: 1.05/mth 70 OFF 12 months: 2.28/mth 35 OFF 1 month: 3. Facebook Watch video from AdLock: 262 views, 1 likes, 0 loves, 0 comments, 0 shares, Facebook Watch Videos from AdLock: Keep your loved ones secure. Its a standalone ad-blocker, capable of protecting you from malware, unwanted advertising, and suspicious websites. AdBlock is the best ad blocker with over 60 million users, and one of the most popular Chrome extensions with over 350 million downloads FEATURES Block pop ups, ads, and annoying banners (even remove video ads) on YouTube, Facebook, Twitch, and all your favorite sites Block third-party trackers and protect your privacy Browse safely by blocking malicious ads with malware. When users are exposed to anonymous ads while they browse, they lose their privacy as their browsing history is being used to manipulate and influence their purchase decisions. AdLock Good all round ad-blocker for Twitch. There are three main reasons users must employ an Ad Blocker while they are browsing, and we will discuss them one by one. ![]() Working systemwide, it blocks all types of commercials: pop-ups, banners, autoplay video ads on all modern browsers (Google Chrome, Opera, Microsoft Edge, Mozilla Firefox) and on apps (Skype, KMPlayer, uTorrent, etc. Adblocker for YouTube Free extension for blocking video ads on YouTube. What difference does Ad Blocker bring in? AdLock is a game-changing ad block for Windows. from Windscribe Ad and tracker blocker that comes with Windscribe VPN. ![]() ![]() ![]() ![]() ![]() Onboard your Riviera Sports Motor Yacht, you will fall under an exotic spell in the absolute lap of luxury, revelling in adventure, exploring, diving, snorkelling, kayaking, fishing, creating and sharing truly memorable moments with family and friends – for as long as your schedule allows or heart desires. Now you and your loved ones can escape the everyday for a weekend or for an extended period to the most alluring ports within your reach. A smooth and quiet ride at speed redefines the class and exceeds expectations.ĭesigned by 4D Designs in collaboration with the Riviera design team and built in-house to our exacting standards on Australia’s Gold Coast, this beautiful new series of sports motor yachts was inspired by a wish list from our global family of experienced Riviera owners seeking to strike out further for longer to celebrate true long-range luxury voyaging the Riviera way. Our Riviera 64 Sports Motor Yacht is in a league of its own, offering signature sports looks, sports performance and a sporting cockpit, renowned Riviera luxury appointments and superior offshore, extended capability. And then, of course, there is the Volvo Penta Glass Cockpit navigation system and silkysmooth and economical performance of twin Volvo Penta IPS turbo diesels with fingertip easy joystick control. This is cruising on an unprecedented scale of comfort and ease. And the 505 SUV adds a dimension to refined living below decks with a full beam master stateroom, private ensuite and walk-in robe as well as two guest staterooms with shared bathroom. World famous, ocean tested, Riviera build quality and strength underpin spirited, enduring performance and retained resale value. And no motor yacht could be more luxurious or better appointed. From bow to boarding platform, you’ll relish the Riviera attention to detail, handcrafted luxury and astonishing operational technology. Marine engines used to propel boats can be categorized into three types: outboard motors, stern drives (inboard-outboard motors), and inboard motors. Anything and everything is possible on board your Riviera 505 SUV. Picture yourself cruising the great waterways of the world, diving in the Bahamas, or fishing on the Reef. And that’s what the cockpit of the 505 delivers. Escape par excellence. The SUV concept demands a generous cockpit, low to the water to maximise the action and adventure of the full spectrum of water sports. To replace an inboard/outboard motor would be much more costly.The Riviera 505 SUV has the same pedigree of a single level alfresco entertainer with thrilling blue-water ability but with the added dimension of the mezzanine: a beautiful wining, dining and relaxing space offering privacy and protection from harsh sun and weather all year round. A boat equipped with an outboard is easier to repower or trade up to more HP or newer technology.In other words, more people want four-stroke outboards.* Fiberglass outboard registrations have historically outpace I/Os.Outboard motors are much more accessible and require less maintenance, no winterizing, and easier to work with the outboard outside the boat.Outboards have a more shallow draft allowing you to fish and boat in skinnier water than you can with an I/O.Typical a four-stroke outboard is approximately 400 to 500 pounds lighter than its inboard/outboard counterpart. Outboards offer better power to weight ratio.Four-stroke outboards offer much better fuel economy, less GPH, more MPG than I/O motors.The Yamaha four strokes offer higher performance–quicker to plane, quicker 0 to 30 MPH, and faster top-end per HP.I/O engines are in the cockpit which takes up a lot of the boat that can be used for other features and comfort. Outboards provide more room in the boat because they are installed on the transom, outside the boat.Inboard/outboards are just “marinized” automobile engines stuck in a boat. Outboards are designed specifically for boating.But here’s where things often get confusing: straight-shaft drives are commonly just called inboards by most people, yet stern drives and pod drives, which are all radically different propulsion systems, are technically also inboards. So why should you choose an outboard over a inboard/outboard motor? Here are just a few advantages the outboard has over the stern drives: Inboard Engines Simply put, inboard engines are those that reside inside the hull of a boat. That’s why all of NauticStar’s Deck Boats are factory installed with high performance Yamaha outboard motors. ![]() Inboard/Outboard Stern Drive Posted on MaJby NAUTICSTAR BOATSįour-stroke outboard motors are becoming increasingly popular over inboard/outboard stern drive motors on pleasure and ski boats for a variety of reasons. ![]() ![]() ![]() I read the reviews since I was curious what changed, and it left me with a frown. Back then everything was free and it was amazing! After downloading some other games of my past, I stumbled across The Smurf’s Bakery. In my past I would play this game soooo often, it’s hard to count. So you see….the smurfs were my childhood, this game was my childhood. ![]() The Smurfs Bakery ©2014 Budge Studios Inc. Contact us 24/7 at and BUDGE STUDIOS are trademarks of Budge Studios Inc. We always welcome your questions, suggestions and comments. Visit us: Like us: /budgestudiosįollow us: our app trailers: /budgestudios Budge Playgroup™ is an innovative program that allows kids and parents to actively participate in the creation of new apps. Budge Studios maintains the highest standards of safety and age-appropriateness, and has become a global leader in children’s apps for smartphones and tablets. Its high-quality app portfolio consists of original and branded properties, including Barbie, Thomas & Friends, Strawberry Shortcake, Caillou, The Smurfs, Miss Hollywood, Hello Kitty and Crayola. This application is subject to an End-User License Agreement available through the following link: īudge Studios was founded in 2010 with the mission to entertain and educate children around the world, through innovation, creativity and fun. These photos are never shared with other users in-app, nor are they shared by Budge Studios with any unaffiliated third party companies. Please note that this app gives users the ability to take photos in-app that can be saved locally on their devices. The app may also contain social media links that are only accessible behind a parental gate. Budge Studios does not permit behavioral advertising or retargeting in this app. ![]() This app may contain contextual advertising (including the option to watch ads for rewards) from Budge Studios regarding other apps we publish, from our partners and some third parties. To disable or adjust the ability to make in-app purchases, change your device settings. In-app purchases cost real money and are charged to your account. For more information, please visit our privacy policy at:, or email our Data Protection Officer at: you download this app, please note that it is free to play, but additional content may be available via in-app purchases. This application has received the “ESRB (Entertainment Software Rating Board) Privacy Certified Kids’ Privacy Seal”. Save and share your recipe to make it at homeīudge Studios takes children's privacy seriously and ensures that its apps are compliant with privacy laws.Complete the Smurfs’ special orders to get stars.Movement-activated gameplay like tilt device to pour. ![]() Choose from different food coloring, sprinkles, figurines and more.Different gameplay mechanics for each dessert so there’s always a challenge.Make Smurfberry Ice Pops, Smurfberry Shakes, Princess Smurfette Cakes, Smurf Head Cake Pops, and Smurf House Cakes!.Simple step-by-step instructions and baking tips from Smurfette.Once you’ve created the smurfiest dessert, test out the recipe at home! Fancy a Smurfberry Ice Pop? Choose a flavor, try out different chocolate dips and get creative with toppings. Create the Smurfiest desserts with fun decorations!īudge Studios™ presents The Smurfs Bakery! Join Smurfette in the kitchen and whip up delectable desserts. ![]() ![]() ![]() Since the HERE SDK encourages the use of Lambda expressions, Java 8 or newer is required. On you can find the latest release artifacts including the HERE SDK framework archive to include in your application (named xx.yy.zz.release_date).Ĭopy the HERE SDK AAR file (*.aar) to your application's app/libs folder. Let's begin with the first step to see how we can add the HERE SDK to our project. The rendering of the map view is optimized for mobile device GPUs. The overall performance will be better, and some features like gestures are just easier to use on multi-touch enabled hardware. Note: While all of the functionalities of the HERE SDK are accessible from the emulator, usage of a real device is strongly recommended. Add the code to load your first map scene.Add a map view to your main activity's layout file.Set required credentials and permissions.Adapt your gradle script to integrate the HERE SDK.Once we have a working Android application, it's time to include the HERE SDK and to show a map on your emulator or device. If all goes well, you should see the "Hello World" text. Once the wizard finishes, make sure to build the plain project and execute it on an emulator (or on a device). If not done already, in Android Studio click Refactor -> Migrate to AndroidX. We recommend to use AndroidX support libaries. Make sure an appropriate directory is chosen in "Save location" and click Finish to continue.Next to "Minimum API level", set API 21 as the minimum Android SDK.For the example below, we have chosen Java. "HelloMap" and select Java or Kotlin as the language. Choose Phone and Tablet, select Empty Activity and click Next.Start Android Studio (for this guide, we have used version Bumblebee 2021.1.1 Patch 2) and create a new project by selecting: The example code for "HelloMap" is available from here. Now you are ready to open the project with Android Studio and you can instantly execute the app on your device or simulator. Insert your HERE credentials ( access_key_id and access_key_secret) in the MainActivity.java file.Add the HERE SDK framework to the app's libs folder.The easiest way to get started, is to try one of the many example projects that are available for the HERE SDK. See also the below section Authenticating Applications to learn more details on how to set the credentials for an app. The APP ID is only relevant for the Lite Edition and the Explore Edition and has no use for other editions. These IDs are not needed by the public APIs of the HERE SDK, but they can be useful when contacting the HERE support team. When you obtain your credentials, also a or an APP ID is shown. For the Navigate Edition you need to contact your HERE representative to generate a set of evaluation credentials. For example, they will work with all example apps you can find on GitHub. Note that these credentials can be reused for the Lite and Explore Editions regardless of the platform - furthermore, you can use these credentials for more than one app. Once registered, you can create credentials. Alternatively, on the HERE platform portal go to your apps page and register a new app.Then scroll down to the HERE SDK product family and click Create a Key. You can either choose an existing project or Select a plan for a new project. ![]()
![]() The Spritelings are the key to progression in The Wild at Heart. It is also easy to switch between types with the click of a button. You can choose how many of each kind of Spriteling you have at any one time. You start to gather a small army of the little fellas, and by commanding them, you can launch them to build bridges, gather cogs and mechanical parts, burn tumbleweeds, and clear poisonous paths. Spritelings also fight enemies, and discover various treasures and items. These tiny creatures help you to move onto new areas and solve puzzles to help you progress. The Wild at Heart: The Spritelings are key It’ll make you utilise the most important aspect of the game: the Spritelings. As you understand more about the story and who these Guardians are, the Deep Woods open up. There, you’ll uncover a fantastical tale about Guardians, magic, and most importantly, friendship. Starting off with a boy called Wave, you find yourself travelling into a mysterious place known as the Deep Woods. The Wild at Heart follows the story of two friends who escape their homes due to difficult childhoods. It’ll also pull at your heartstrings as your adventure takes you deep into the woods. It’s a hand-drawn puzzler with Metroidvania elements and bags of charm. Breath of the Wild, Pikmin, and Where the Wild Things Are are just a handful of them. ![]() There are plenty of genres and inspirations throughout. I’d not heard much about The Wild at Heart, but from the second I started to play, I could tell it was something special. Every now and again, a game comes out of nowhere and really surprises you. ![]() ![]() PART 2 IN ROCKSTAR OMEGA JUNGKOOK & ALPHA NAMJOON SERIES ![]() Namjoon just really loves hand feeding Jungkook.It does not go well.) Language: English Words: 10,879 Chapters: 5/? Comments: 65 Kudos: 300 Bookmarks: 62 Hits: 4398Įllemoonchild Fandoms: 방탄소년단 | Bangtan Boys | BTS (Or: Nepo baby Seokjin meets rockstar Jungkook. Is a decade enough to heal old wounds? And what happens when people find out that perhaps he hasn’t given up on music as much as they thought? ![]() There, he encounters rising star Jeon Jungkook, and life starts to get interesting again. Ten years later, however, he is called back to L.A. Trying to heal from his experiences with bullying, he settles for a quiet life in Seoul, giving up on his dreams of becoming a singer. Kim Seokjin left Los Angeles behind after becoming a viral but mortifying sensation at the age of 14.
![]() ![]() ![]() ![]() “This raised the level of urgency for the Pac-12 to match and respond and they did. “We needed to be united and not fall behind the Big 10 and SEC,” Farden said. After this, the hope is that the neutral site is a hit and some other venue in another Pac-12 city is ready to be the next to pick up the torch. Pac-12 gymnastics powers-that-be vetted other potential venues and candidate cities for the first three years of this endeavor, but they chose the Salt Lake Valley first. First-round games are scheduled to start Thursday, March 21, and continue two days later on March 23, guaranteed to make that weekend a college sports spectacle. That’s the same day as second-round matchups of the 2019 NCAA men’s basketball tournament is scheduled to be played in Salt Lake City at the Vivint Smart Home Arena. The 2019 Pac-12 championships will be held Saturday, March 23, 2019. Utah is coming off a fifth-place finish nationally in 2018 as conference rival UCLA took home the national title. The Huntsman Center has twice hosted the Pac-12 Championships, in 20. The Red Rocks are among the top programs in the country, sporting three Pac-12 titles and three runner-up finishes in their seven seasons since joining the Pac-12. “That decision was in their hands, but I can’t help but think the way the state of Utah has embraced gymnastics and the way the city of Salt Lake has embraced the Red Rocks program, I can’t help but think that was a feather in the cap of our program,” Farden said. Having a raucous devoted fan base helps, too. The Big 12 announced last Friday it extended formal invitations to BYU, Cincinnati, Houston and UCF to join the conference starting with the 2023-24 athletic year. While the conference office made the decision to pick West Valley City as its first neutral site, it certainly didn’t hurt that Utah’s reputation in the sport is among the country’s elite. “It makes it feel very special to our athletes.” 2 Oklahoma into the Lloyd Noble Center for a conference tri meet. “It was important to mimic the other conferences and to give our athletes an opportunity to prepare for championship postseason performances,” Utah co-head coach Tom Farden said. The 2012 Big 12 gymnastics championship brought No. With both the Big 10 and SEC having adopted a podium-style championships, the Pac-12 felt it was time to follow suit. It was a unanimous decision from all Pac-12 coaches that the conference’s annual championship meet needed to be on a podium, like nationals each year and the Olympics every four-year cycle. The Maverik Center appealed to the Pac-12’s elite by featuring a podium equipment set up, similar to what the annual NCAA Championships are conducted on every year. “With a rich tradition of excellence across the sport and a strong following among Utah’s community, we look forward to this showcase featuring some of the top gymnasts in the world competing at Maverik Center.” “The Pac-12 is thrilled to bring one of our premiere events to the Salt Lake Valley,” said Pac-12 Senior Associate Commissioner, Sports Management Teresa Gould in a release. ![]() ![]() ![]() ![]() Choose the download for your operating system below, extract the archive to a new folder and run it.Java Runtime Environment 1.8.0 How to install: Import modpacks from various platforms.Import and export of Minecraft instances to share them with anyone.Minecraft world and resource/texture pack management.MultiMC is a huge improvement over the vanilla Minecraft launcher and it makes setting up profiles and managing your play experience very simple. To install Fabric for MultiMC, edit an instance and select the 'Fabric Install Button'. MultiMC is a free and open-source launcher for Minecraft (it will completely replace the regular Mojang supplied launcher) that does an absolutely spectacular job of managing your Minecraft experience. Easy installation of common mod loaders – Forge, Fabric and LiteLoader (and likely more incoming). MultiMC was the first launcher (albeit third-party) to support the Fabric Modloader. ![]() MultiMC is extremely lightweight, enabling it to run in the background and keeping an eye on the game even on ancient machines where every megabyte of memory matters.Kill Minecraft easily if it crashes / freezes.Support for running old versions the way they were released, instead of relying on compatibility hacks. How To Install 'Fabric' 1.16 Versions On MultiMC Install Tutorial (Applies to all snapshot/release) Niche Duck 2.MultiMC game logs come with extra information that helps diagnose problems, and they are color coded.After upgrading the Fabric to the newest version, you can also check the status of the API. From the versions menu in MultiMC, confirm whether the update is successful, then delete the fabric folder inside the Minecraft file. Each instance has settings overrides that you can enable on top of the global settings. Afterward, locate the file from patches in the instance folder and overwrite it on the previous file. Fine control over Java settings and runtimes.A quick & dirty way to get Minecraft running via MultiMC on the Apple M1. So you want to use a mod like Replay for Minecraft but also want the aesthetic that comes with a really nice shader pack OptiFine is no longer compatible with Forge as of the Minecraft 1.13 update, but we know a workaround. No surprises – MultiMC aims to stay predictable and do what you tell it to do. Compare sodium-fabric vs m1-multimc-hack and see what are their differences.Drill into the details – see the logs, mods and everything else easily.Manage multiple isolated instances of Minecraft, keeping them clean.It allows you to have multiple, cleanly separated instances of Minecraft (each with their own mods, resource packs, saves, etc) and helps you manage them and their associated options with a simple and powerful interface. This launcher focuses on predictability, long term stability and simplicity. MultiMC Launcher (1.19.4, 1.18.2) is a custom launcher for Minecraft that allows you to easily manage multiple installations of Minecraft at once. MultiMC Launcher (1.19.4, 1.18.2) Download Links. ![]() ![]() ![]() On the LCD and continues irrigation for the rest of the valves. Of the vales simultaneously while automatic short circuitĭetection isolates the shorted valve, provides a visible "alarm" Rain Delay of up to 30 days and auto re-start.Īutomatic, Semi-automatic and manual mode for each valve or all Monthly Water Budgeting can be used to adjust irrigation from 10% Of preventing irrigation in areas that are exposed to rain (lawn)Īnd allowing irrigation to areas that are not exposed to rain The sensor input isĪssigned to individual valves providing you with the flexibility The available sensor input can be used with a rain sensor, soil Galcon Six Station Indoor Irrigation, Misting and Propagation Controller - 8056S (AC-6S) (10/Cs) This indoor irrigation and propagation controller operates up to 4 or 6 (depending on model selection) control valves with a master valve or pump start. Window will limit watering to desired hours of operation. Long as 12 hours with a cycle as short as every 1 minute to as In Cyclical mode, irrigation duration as short as 1 second to as Irrigation duration as short as 1 minute to as long as 12 hoursĪnd up to 4 start times per valve may be used. Programming can be set by day of the week (Daily/Weekly) with Offers the ultimateįlexibility in scheduling by offering independent programming ofĮach valve and the ability to operate two valves simultaneously. TheĨ056S AC 6S features a large easy-to-program LCD screen and Fourīuttons for programming. Resistance and delivered in a water-tight outdoor enclosure. In addition to outstanding durability that has be tested for UV Designed to operate up to 6 IrrigationĬontrol Valve. The Galcon 8056S AC 6S is an Indoor or Outdoor Irrigation and Imported from USA (Sizes & Specifications are based on the USA Market). ![]() ![]() Operates 6 valves plus master valve in Seconds Minutes and Hours Great for Irrigation Misting and Propagation Designed for indoor or Outdoor installations Sensor Input Daily or Cyclic programming This product is designed for use only in the USA and Canada. ![]() |